Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate

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Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolyl­amino)-1,2,5,6-tetra­hydro­pyridine-3-carboxyl­ate

In the title compound, C(33)H(32)N(2)O(2), the tetra-hydro-pyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetra-hydro-pyridine ring. The mol-ecular conformation is stabilized by intra-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions. Formation of centrosymmetric head-to-head dimers is observed through pair...

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4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate

In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (-), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the mol-ecules to form an infinite one-dimensional chain paral...

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4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium perchlorate

In the title compound, C(22)H(19)N(2) (+)·ClO(4) (-), the three pendant aromatic rings are twisted from the plane of the imidazolium ring by dihedral angles of 17.3 (2), 65.7 (2) and 3.4 (2)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the ions, forming a ribbon-like structure along the a axis.

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2-(4,5-Diphenyl-2-p-tolyl-1H-imidazol-1-yl)-3-phenyl­propan-1-ol

In the title compound, C(31)H(28)N(2)O, the dihedral angles formed by the imidazole ring with the three aryl substituents are 18.52 (8) and 85.56 (7) and 85.57 (7)°, respectively. In the crystal, mol-ecules are linked by O-H⋯N and C-H⋯O hydrogen bonds into chains parallel to the a axis.

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6-Methyl-2-p-tolyl-4-[3-(trifluoro­meth­yl)phen­yl]pyridazin-3(2H)-one

In the title mol-ecule, C(19)H(15)F(3)N(2)O, the benzene rings of the tolyl and trifluoro-methyl-phenyl groups form dihedral angles of 64.1 (2) and 38.5 (2)°, respectively, with the pyridazine ring. The CF(3) group is disordered over two orientations, with site-occupancy factors of ca 0.56 and 0.44.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812030309